Ternary organic photodetectors based on pseudo–binaries nonfullerene–based acceptors

The addition of a third component to a donor:acceptor blend is a powerful tool to enhance the power conversion efficiency of organic solar cells. Featuring a similar operating mechanism, organic photodetectors are also expected to benefit from this approach. Here, we fabricated ternary organic photodetectors, based on a polymer donor and two nonfullerene acceptors, resulting in a low dark current of 0.42 nA cm−2 at −2 V and a broadband specific detectivity of 1012 Jones. We found that exciton recombination in the binary blend is reduced in ternary devices due to the formation of a pseudo-binary microstructure with mixed donor–acceptor phases. With this approach a wide range of intermediate open-circuit voltages is accessible, without sacrificing light-to-current conversion. This results in ternary organic photodetector (TOPD) with improved Responsivity values in the near-infrared. Moreover, morphology analyses reveal that TOPD devices showed improved microstructure ordering and consequentially higher charge carrier mobilities compared to the reference devices

Hydrodynamical simulations of convection-related stellar micro-variability. II. The enigmatic granulation background of the COROT target HD49933

Local-box hydrodynamical model atmospheres provide statistical information about a star's emergent radiation field which allows one to predict the level of its granulation-related micro-variability. Space-based photometry is now sufficiently accurate to test model predictions. We aim to model the photometric granulation background of HD49933 as well as the Sun, and compare the predictions to the measurements obtained by the COROT and SOHO satellite missions. We construct hydrodynamical model atmospheres representing HD49933 and the Sun, and use a previously developed scaling technique to obtain the observable disk-integrated brightness fluctuations. We further performed exploratory magneto-hydrodynamical simulations to gauge the impact of small scale magnetic fields on the synthetic light-curves. We find that the granulation-related brightness fluctuations depend on metallicity. We obtain a satisfactory correspondence between prediction and observation for the Sun, validating our approach. For HD49933, we arrive at a significant over-estimation by a factor of two to three in total power. Locally generated magnetic fields are unlikely to be responsible, otherwise existing fields would need to be rather strong to sufficiently suppress the granulation signal. Presently suggested updates on the fundamental stellar parameters do not improve the correspondence; however, an ad-hoc increase of the HD49933 surface gravity by about 0.2dex would eliminate most of the discrepancy. We diagnose a puzzling discrepancy between the predicted and observed granulation background in HD49933, with only rather ad-hoc ideas for remedies at hand.Comment: 7 pages, 5 figures, accepted for publication in A&

The CoRoT target HD175726: an active star with weak solar-like oscillations

Context. The CoRoT short runs give us the opportunity to observe a large variety of late-type stars through their solar-like oscillations. We report observations of the star HD175726 that lasted for 27 days during the first short run of the mission. The time series reveals a high-activity signal and the power spectrum presents an excess due to solar-like oscillations with a low signal-to-noise ratio. Aims. Our aim is to identify the most efficient tools to extract as much information as possible from the power density spectrum. Methods. The most productive method appears to be the autocorrelation of the time series, calculated as the spectrum of the filtered spectrum. This method is efficient, very rapid computationally, and will be useful for the analysis of other targets, observed with CoRoT or with forthcoming missions such as Kepler and Plato. Results. The mean large separation has been measured to be 97.2+-0.5 microHz, slightly below the expected value determined from solar scaling laws.We also show strong evidence for variation of the large separation with frequency. The bolometric mode amplitude is only 1.7+-0.25 ppm for radial modes, which is 1.7 times less than expected. Due to the low signal-to-noise ratio, mode identification is not possible for the available data set of HD175726. Conclusions. This study shows the possibility of extracting a seismic signal despite a signal-to-noise ratio of only 0.37. The observation of such a target shows the efficiency of the CoRoT data, and the potential benefit of longer observing runs.Comment: 8 pages. Accepted in A&

Stochastic excitation of acoustic modes in stars

For more than ten years, solar-like oscillations have been detected and frequencies measured for a growing number of stars with various characteristics (e.g. different evolutionary stages, effective temperatures, gravities, metal abundances ...). Excitation of such oscillations is attributed to turbulent convection and takes place in the uppermost part of the convective envelope. Since the pioneering work of Goldreich & Keely (1977), more sophisticated theoretical models of stochastic excitation were developed, which differ from each other both by the way turbulent convection is modeled and by the assumed sources of excitation. We review here these different models and their underlying approximations and assumptions. We emphasize how the computed mode excitation rates crucially depend on the way turbulent convection is described but also on the stratification and the metal abundance of the upper layers of the star. In turn we will show how the seismic measurements collected so far allow us to infer properties of turbulent convection in stars.Comment: Notes associated with a lecture given during the fall school organized by the CNRS and held in St-Flour (France) 20-24 October 2008 ; 39 pages ; 11 figure

Stellar turbulence and mode physics

An overview of selected topical problems on modelling oscillation properties in solar-like stars is presented. High-quality oscillation data from both space-borne intensity observations and ground-based spectroscopic measurements provide first tests of the still-ill-understood, superficial layers in distant stars. Emphasis will be given to modelling the pulsation dynamics of the stellar surface layers, the stochastic excitation processes and the associated dynamics of the turbulent fluxes of heat and momentum.Comment: Proc. HELAS Workshop on 'Synergies between solar and stellar modelling', eds M. Marconi, D. Cardini, M. P. Di Mauro, Astrophys. Space Sci., in the pres

Properties of high-frequency wave power halos around active regions: an analysis of multi-height data from HMI and AIA onboard SDO

We study properties of waves of frequencies above the photospheric acoustic cut-off of $\approx$5.3 mHz, around four active regions, through spatial maps of their power estimated using data from Helioseismic and Magnetic Imager (HMI) and Atmospheric Imaging Assembly (AIA) onboard Solar Dynamics Observatory (SDO). The wavelength channels 1600 {\AA} and 1700 {\AA} from AIA are now known to capture clear oscillation signals due to helioseismic p modes as well as waves propagating up through to the chromosphere. Here we study in detail, in comparison with HMI Doppler data, properties of the power maps, especially the so called 'acoustic halos' seen around active regions, as a function of wave frequencies, inclination and strength of magnetic field (derived from the vector field observations by HMI) and observation height. We infer possible signatures of (magneto-)acoustic wave refraction from the observation height dependent changes, and hence due to changing magnetic strength and geometry, in the dependences of power maps on the photospheric magnetic quantities. We discuss the implications for theories of p mode absorption and mode conversions by the magnetic field.Comment: 22 pages, 12 figures, Accepted by journal Solar Physic

Solar-like oscillations with low amplitude in the CoRoT target HD 181906

Context: The F8 star HD 181906 (effective temperature ~6300K) was observed for 156 days by the CoRoT satellite during the first long run in the centre direction. Analysis of the data reveals a spectrum of solar-like acoustic oscillations. However, the faintness of the target (m_v=7.65) means the signal-to-noise (S/N) in the acoustic modes is quite low, and this low S/N leads to complications in the analysis. Aims: To extract global variables of the star as well as key parameters of the p modes observed in the power spectrum of the lightcurve. Methods: The power spectrum of the lightcurve, a wavelet transform and spot fitting have been used to obtain the average rotation rate of the star and its inclination angle. Then, the autocorrelation of the power spectrum and the power spectrum of the power spectrum were used to properly determine the large separation. Finally, estimations of the mode parameters have been done by maximizing the likelihood of a global fit, where several modes were fit simultaneously. Results: We have been able to infer the mean surface rotation rate of the star (~4 microHz) with indications of the presence of surface differential rotation, the large separation of the p modes (~87 microHz), and therefore also the ridges corresponding to overtones of the acoustic modes.Comment: Paper Accepted to be published in A&A. 10 Pages, 12 figure

High efficiency blue organic light-emitting diodes with below-bandgap electroluminescence

Blue organic light-emitting diodes require high triplet interlayer materials, which induce large energetic barriers at the interfaces resulting in high device voltages and reduced efficiencies. Here, we alleviate this issue by designing a low triplet energy hole transporting interlayer with high mobility, combined with an interface exciplex that confines excitons at the emissive layer/electron transporting material interface. As a result, blue thermally activated delay fluorescent organic light emitting diodes with a below-bandgap turn-on voltage of 2.5 V and an external quantum efficiency of 41.2% were successfully fabricated. These devices also showed suppressed efficiency roll-off maintaining an EQE of 34.8% at 1000 cd m-2. Our approach paves the way for further progress through exploring alternative device engineering approaches instead of only focusing on the demanding synthesis of organic compounds with complex structures

Modeling the Subsurface Structure of Sunspots

While sunspots are easily observed at the solar surface, determining their subsurface structure is not trivial. There are two main hypotheses for the subsurface structure of sunspots: the monolithic model and the cluster model. Local helioseismology is the only means by which we can investigate subphotospheric structure. However, as current linear inversion techniques do not yet allow helioseismology to probe the internal structure with sufficient confidence to distinguish between the monolith and cluster models, the development of physically realistic sunspot models are a priority for helioseismologists. This is because they are not only important indicators of the variety of physical effects that may influence helioseismic inferences in active regions, but they also enable detailed assessments of the validity of helioseismic interpretations through numerical forward modeling. In this paper, we provide a critical review of the existing sunspot models and an overview of numerical methods employed to model wave propagation through model sunspots. We then carry out an helioseismic analysis of the sunspot in Active Region 9787 and address the serious inconsistencies uncovered by \citeauthor{gizonetal2009}~(\citeyear{gizonetal2009,gizonetal2009a}). We find that this sunspot is most probably associated with a shallow, positive wave-speed perturbation (unlike the traditional two-layer model) and that travel-time measurements are consistent with a horizontal outflow in the surrounding moat.Comment: 73 pages, 19 figures, accepted by Solar Physic

Infrared organic photodetectors employing ultralow bandgap polymer and non-fullerene acceptors for biometric monitoring

Recent efforts in the field of organic photodetectors (OPD) have been focused on extending broadband detection into the near-infrared (NIR) region. Here, two blends of an ultralow bandgap push–pull polymer TQ-T combined with state-of-the-art non-fullerene acceptors, IEICO-4F and Y6, are compared to obtain OPDs for sensing in the NIR beyond 1100 nm, which is the cut off for benchmark Si photodiodes. It is observed that the TQ-T:IEICO-4F device has a superior IR responsivity (0.03 AW-1 at 1200 nm and −2 V bias) and can detect infrared light up to 1800 nm, while the TQ-T:Y6 blend shows a lower responsivity of 0.01 AW-1. Device physics analyses are tied with spectroscopic and morphological studies to link the superior performance of TQ-T:IEICO-4F OPD to its faster charge separation as well as more favorable donor–acceptor domains mixing. In the polymer blend with Y6, the formation of large agglomerates that exceed the exciton diffusion length, which leads to high charge recombination, is observed. An application of these devices as biometric sensors for real-time heart rate monitoring via photoplethysmography, utilizing infrared light, is demonstrated